Journal
RUSSIAN CHEMICAL BULLETIN
Volume 71, Issue 1, Pages 102-106Publisher
SPRINGER
DOI: 10.1007/s11172-022-3382-9
Keywords
adamantane; skeletal isomerization; ionic liquids; sulfuric acid; tricyclodecane; pentacyclodecane
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Funding
- Russian Science Foundation [19-73-20128]
- Ministry of Science and High Education of the Russian Federation [AAAA-A19-119022290009-3/FMRS-2022-0076]
- Regional Center for Collective Use of Unique Equipment Agidel at the Institute of Petrochemistry and Catalysis, UFRC RAS [AAAA-A19-119022290004-8]
- Russian Science Foundation [19-73-20128] Funding Source: Russian Science Foundation
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This paper describes the synthesis of adamantane through skeletal isomerization and hydroisomerization methods. The new method showed a significant improvement in yield.
Adamantane was synthesized by skeletal isomerization of endo- and exo-tricyclo[5.2.1.0(2,6)]-decanes in the presence of ionic liquid [Et3NH](+)[Al2Cl7](-)-CuSO4. A new method to synthesize adamantane in 75% yield by H2SO4-mediated hydroisomerization of its new precursor, pentacyclo[4.4.0.0(2,4).0(3,7).0(8,10)]decane, was developed.
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