4.4 Review

Recent advances in dual-filler mixed matrix membranes

Journal

REVIEWS IN CHEMICAL ENGINEERING
Volume 39, Issue 3, Pages 449-478

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/revce-2021-0014

Keywords

composite filler; composite membrane; dual-filler; mixed matrix membrane; synergistic effect

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This article reviews the recent development of mixed matrix membranes (MMMs) with dual filler and discusses their performances in diverse potential applications. The use of dual filler instead of a single filler can achieve multiple effects, but this emerging field still faces challenges.
Mixed matrix membranes (MMMs) have been widely developed as an attractive solution to overcome the drawbacks found in most polymer membranes, such as permeability-selectivity trade-off and low physicochemical stability. Numerous fillers based on inorganic, organic, and hybrid materials with various structures including porous or nonporous, and two-dimensional or three-dimensional, have been used. Demanded to further improve the characteristics and performances of the MMMs, the use of dual-filler instead of a single filler has then been proposed, from which multiple effects could be obtained. This article aims to review the recent development of MMMs with dual filler and discuss their performances in diverse potential applications. Challenges in this emerging field and outlook for future research are finally provided.

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