Journal
INORGANICA CHIMICA ACTA
Volume 453, Issue -, Pages 574-582Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2016.08.040
Keywords
Coordination compounds; Coordination polymers; Copper complexes; Rhodium complexes; 6-Methylpicolinic ligand; Supramolecular networks
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Funding
- Spanish Ministerio de Economia y Competitividad [MAT2013-46502-C2-2P, MAT2013-46753-C2-1P]
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Seven new coordination compounds with 6-methylpicolinic acid (6-HMepic) and rhodium(III) or copper (II) of formula [Rh(6-mepic)(3)] (1), [Ith(6-Mepic)(2)(H2O)Cl] (2), [Rh(6-HMepic)(6-Mepic)Cl-2].3.5(H2O) (3), [Cu(6-Mepic)(2)(H2O)].H2O (4), [Cu(6-Mepic)(2)](n), (5), [Cu(6-Mepic)(6-HMepic)I] (6) and [Cu(6-Mepic)(6HMepic)Cl] (7) have been obtained. Their syntheses have been rationalized, and their structural and supramolecular characteristics have been studied and compared with other similar rhodium and copper picolinate complexes previously reported, in order to stablish structural correlations and analogies. The electrical properties of coordination polymeri[Cu(6-Mepic)(2)](n) (5) have been also analyzed and it has been found that it shows a moderated electrical transport along the chain. (C) 2016 Published by Elsevier B.V.
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