Journal
INORGANIC CHEMISTRY
Volume 55, Issue 20, Pages 10090-10093Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01089
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Funding
- Hungarian Research Fund (OTKA) [K108489]
- Hungarian Academy of Sciences
- Ministry of Human Resourches
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The chiral pentadentate low-spin (S = 1) oxoiron(IV) complex [Fe-IV(O)(asN4Py)](2+) (2) was synthesized and spectroscopically characterized. Its formation kinetics, reactivity, and (enantio)selectivity in an oxygen-atom-transfer reaction was investigated in detail and compared to a similar pentadentate ligand-containing system.
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