Journal
INORGANIC CHEMISTRY
Volume 55, Issue 13, Pages 6776-6780Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01092
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Funding
- China Scholarship Council (CSC) of the People's Republic of China
- University of Bordeaux
- University of Toulouse 3
- LCC (Toulouse)
- Centre National de la Recherche Scientifique (CNRS)
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Mono-, bis-, and tris-1,2,3-triazole ligands are used for the stabilization of gold nanoparticles (AuNPs), and the catalytic activities of these AuNPs in 4-nitrophenol reduction by NaBH4 in water are compared as well as with polyethylene glycol 2000 (PEG)- and polyvinylpyrrolidone (PVP)-stabilized AuNPs. The excellent catalytic results specifically obtained with the tris-triazolate ligand terminated by a PEG tail are taken into account by the synergy between the weakness of the tris-triazole-AuNP bond combined with the stabilizing ligand bulk.
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