4.7 Article

Molecular Scissoring: Facile 3D to 2D Conversion of Lanthanide Metal Organic Frameworks Via Solvent Exfoliation

Journal

INORGANIC CHEMISTRY
Volume 55, Issue 21, Pages 10851-10854

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02222

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Funding

  1. Ministry of Education, Singapore, NUS FRC Grant [R-143-000-604-112]

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Five lanthanide MOFs with pcu topology have been exfoliated into nanoplatelets of two-dimensional structures via sonication in the dimethylacetamide solvent. These nanosheets are fluorescent under two-photon excitation dominated by the ligand, indicating energy upconversion ability.

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