4.7 Article

Robust Metal-Organic Framework Containing Benzoselenadiazole for Highly Efficient Aerobic Cross-dehydrogenative Coupling Reactions under Visible Light

Journal

INORGANIC CHEMISTRY
Volume 55, Issue 3, Pages 1005-1007

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02626

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Funding

  1. NSFC [21302072, 51403081, 21376113]
  2. NSF of Jiangsu Province [BK20130226, BK20140137]
  3. PAPD of Jiangsu Higher Education Institutions

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A zirconium(IV)-based UiO-topological metal-organic framework (UiO-68Se) containing benzoselenadiazole was synthesized by an approach of the mixed dicarboxylate struts, which show highly efficient and recycalable photocatalytic activity for aerobic cross-dehydrogenative coupling reactions between tertiary amines and various carbon nucleophiles under visible-light irradiation.

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