4.7 Article

Delocalized Hypervalent Silyl Radical Supported by Amidinate and Imino Substituents

Journal

INORGANIC CHEMISTRY
Volume 56, Issue 2, Pages 701-704

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02427

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Funding

  1. AcRF Tier 1 [RG06/14]

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The reaction of the amidinato silylsilylene with a functionalized diaminochlorosilyl substituent, [LSiSi(Cl){(NtBu)(2)C(H)Ph}] (1; L = PhC(NtBu)(2)), with ArN=C=NAr (Ar = 2,6-iPr(2)C(6)H(3)) in toluene afforded the delocalized hypervalent silyl radical [LSi center dot(mu-CNAr)(2)Si{(NtBu)(2)C(H)Ph}] (2). It possesses a hypervalent silyl radical that delocalizes throughout the Si2C2 ring.

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