4.7 Article

A Clear Insight into the Distinguishing CO2 Capture by Two Isostructural DyIII-Carboxylate Coordination Frameworks

Journal

INORGANIC CHEMISTRY
Volume 55, Issue 13, Pages 6352-6354

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b00760

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Funding

  1. National Natural Science Foundation of China [21571158]
  2. Innovation Scientists and Technicians Troop Construction Projects of Henan Province [152101510003]
  3. Program for Science & Technology Innovative Research Team in University of Henan Province [15IRTSTHN-002]

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Two isostructural the-type Dy-III coordination networks were successfully constructed based on a pair of analogous tribenzoate bridging ligands with phenyl and triazinyl central spacers. Notably, the active triazinyl group can obviously enhance the capability and selectivity of CO2 sorption for the porous framework.

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