Journal
INORGANIC CHEMISTRY
Volume 55, Issue 7, Pages 3332-3337Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.5b02582
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Funding
- KAKENHI [26288026, 2506]
- JSPS [15K17833]
- Cooperative Research Program of Network Joint Research Center for Materials and Devices
- Grants-in-Aid for Scientific Research [26288026, 15J11333, 15K17833] Funding Source: KAKEN
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Metal dilution effects on reverse spin transition (rST) in mixed crystals of type [Co1-xZnx(C-16-terpy)(2)](BF4)(2) (x = 0.1-0.7) were investigated by comparison with behavior of [Co1-xFex(C-16-terpy)(2)](BF4)(2) (x = 0.1-0.4). In the mixed crystals, the Zn complexes increased, rST temperatures linearly with increasing values of x, without changing the hysteresis width, while the Fe complexes decreased rST temperatures. Moreover, the strength of the metal dilution effects in the CoZn mixed crystals is weaker than what occurs in the CoFe mixed crystals.
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