Journal
POLYMER
Volume 234, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2021.124260
Keywords
Recycled PET; Supersonic solution blowing; Particulate matters; Facemask; Reusability
Categories
Funding
- DST-SERB [ECR/2017/001511]
- IIT-Mandi [IITM/SG/SSR/60]
- Ministry of Education (MoE), Govt. of India
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Research has shown that nanofiber mats made from waste plastic bottles using supersonic solution blowing technology have high particle filtration efficiency for PM0.1-2, with finer fibers allowing for better capture of particles and reduced pressure drop. The porous nature of the supersonic solution blowing fiber mat also exhibited more hydrophobic properties compared to electrospun fiber mats, making it suitable for long-term use in facemasks with washable capabilities.
Air pollution with enhanced concentration of particulate matters (PM0.1-10) have worsened from last decade. Although the demand of facemasks has sky-rocketed during current pandemic, the importance of fibrous air filtration unit, as personal protection equipment, was recognized several years ago. In this work, we have developed nanofiber mats from waste plastic bottles (polythyleneterepthalate, PET) by electrospinning (ES) and supersonic solution blowing (SSB) for filtration of PM0.1-2. The latter could manufacture nanofibers as fine as 1/3rd of former from same polymer concentration via enhanced strain rate. SSB nanofibers, sandwiched between two cotton clothes, demonstrated 99.7% particle filtration efficiency (PFE) for PM2 at air flow rates 80 L per minute (LPM) with 11.56 Pa/cm(2) pressure drop (Delta P) and quality factor (QF) of 0.03 Pa-1. The finer fibers allowed a transition flow across mat, reducing Delta P, whereas enhanced interaction between fibers and particles along with reduced drag, emphasized diffusion capture of PMs. Porous SSB fiber mat was more hydrophobic than ES fiber mat. Also, a prototype facemask with SSB mat showed PFE at PM0.2 and 80 LPM flow rate mere 4% reduction after 21 days. Such facemask was washable and after 10 cycles of regular handwashing and sun drying it could still retail >99% PFE for PM2.
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