Journal
INORGANIC CHEMISTRY
Volume 55, Issue 7, Pages 3680-3684Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b00252
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Funding
- National Natural Science Foundation of China [21202020, 21572032]
- Doctoral Fund of Ministry of Education of China [20123514120002]
- Natural Science Foundation of Fujian Province [2014J01040, 2014J01045]
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Host-guest encapsulation of electron-rich naphthalene molecules into a weakly emissive porous metal-organic framework based on pi-electron-deficient (pi-acidic) naphthalene diimide tectons leads to orange-emissive crystals, which can be used to sense strongly basic organic amines in a fast response, high photostability, and tunable sensitivity. Moreover, such host-guest inclusion crystals are also a good photochromic probe for the detection of weakly basic N-methyl-2-pyrrolidone and N,N-dimethylformamide molecules.
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