Journal
INORGANIC CHEMISTRY
Volume 55, Issue 22, Pages 11613-11616Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01619
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Funding
- Japan Society for the Promotion of Science [26288024, 25410067]
- Ministry of Education, Culture, Sports, Science, and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [26410071, 26288024, 25410067] Funding Source: KAKEN
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Three Ru-CO complexes, [Ru(Pbn)(2)(CO)(2)](2+), [Ru(pbn)(2)(CO)(COOH)(+), [Ru(pbn)(2)(CO)(COO)](0) [pbn = 2-(pyridin-2-yl)benzo[b]1,5-naphthyridine], exist as equilibrium mixtures in aqueous solutions. Thermal decarboxylation of [Ru(pbn)(2)(CO)(COOH)(+) and/or [Ru(pbn)(2)(CO)(COO)](0) induces a two -electron reduction of pbn to form [Ru(pbn)(pbnHH)(CO)(OH2)](2+) [pbnHH = 2-(pyridin-2-y1)-5,10-dihydrobenzo [b] -1,5-n aphthyridin e] in H2O.
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