Journal
INORGANIC CHEMISTRY
Volume 55, Issue 21, Pages 11110-11124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01736
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Funding
- Strategic International Collaborative Research Program (SICORP) of JST
- All Nippon Artificial Photosynthesis Project for Living Earth (AnApple) of JSPS
- Grants-in-Aid for Scientific Research [24107005] Funding Source: KAKEN
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Vinylene or ethynylene linkers in the bridging ligands of photofunctional multinuclear complexes synthesized by various coupling reactions, such as the Mizoroki-Heck reaction, olefin metathesis, and Sonogashira coupling, were successfully converted to their corresponding saturated carbon chains using photochemical hydrogenation, which proceeded in an MeCN- pyridine-CF3COOH (3:1:0.1 v/v/v) mixed solution containing the starting metal complexes and 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH) as a sacrificial electron donor under-visible light irradiation in high yields. Hydrogenation of linkers in a Ru-2-Re trinuclear complex improved the photocatalytic ability for CO2 reduction.
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