Journal
INORGANIC CHEMISTRY
Volume 55, Issue 15, Pages 7311-7313Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b00429
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Funding
- 973 Program of China [2012CB821701]
- NSFC [91222201, 21373276]
- China Postdoctoral Science Foundation [2015M572398]
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We demonstrate that the conformation, packing mode, and blue fluorescence of a soft piezo-fluorochromic compound can be preserved by structurally fixing it into a solid calcium metal-organic framework (Ca-MOF, LIFM-40), which can survive pressures up to 8 MPa. DFT calculations have been combined with experimental results to inditate that the ligands adopting a specific conformation and packing without pi...pi interactions are the reasons for its rigidified blue emission.
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