4.8 Article

Second-Order Real Nodal-Line Semimetal in Three-Dimensional Graphdiyne

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Summary: Higher-order and real topological phases are emerging topics in the field of topological states of matter, with graphyne identified as a 2D second-order topological insulator and real Chern insulator. The unique properties of graphyne, including double band inversion and three valleys, are characterized by a real Chern number enabled by spacetime-inversion symmetry. Topological corner states are found to exist in graphyne, with a topological phase transition to a trivial insulator mediated by a 2D Weyl semimetal phase. The robustness of corner states against symmetry breaking and possible experimental detection methods are also discussed.

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