4.6 Article

Highly oriented platinum/iridium thin films for high-temperature thermocouples with superior precision

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 24, Issue 10, Pages 6163-6168

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp05196b

Keywords

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Funding

  1. National Natural Science Foundation of China [61704006]
  2. Beijing Nova Programme Interdisciplinary Cooperation Project [Z191100001119013]
  3. Scientific Research Project of Beijing Educational Committee [KM202111232015]
  4. Supplementary and Supportive Project for Teachers at Beijing Information Science and Technology University [5029011103]
  5. Key Project of Independent Innovation Special Fund, AECC [JK65200309]

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This study focuses on a new strategy of reducing alloys for the easy preparation and performance enhancement of thin-film thermocouples (TFTCs) through nanostructure and interface design. A platinum/iridium (Pt/Ir) TFTC with a well matched interface and few defects is fabricated, showing excellent long-term service stability over a high-temperature range. The Pt/Ir TFTCs exhibit significant potential for various applications such as thermal detection, microelectronics, and aero-engines.
The long-term precise high-temperature measurement of thin-film thermocouples (TFTCs) has attracted attention due to the capability of instantaneous temperature detection. However, related technologies have seen slow development, and there is no one standard TFTC yet. Here, we focus on a new strategy of reducing alloys for the easy preparation and performance enhancement of TFTCs via nanostructure and interface design. To this end, we fabricated a platinum/iridium (Pt/Ir) pure-element TFTC with a well matched interface and few defects, which demonstrated excellent long-term service stability over a high-temperature range. The corresponding polynomial fitting coefficients were >= 0.99999, indicating the accurate acquisition of temperature data. A reduced deviation (<0.21%) between three calibration cycles was obtained over a wide temperature range of 300 degrees C to 1000 degrees C, which is better than the maximum precision of a standard wire thermocouple. Superior properties are achieved because of the resulting fewer defects in the Pt and Ir thin films with highly preferential orientation along the (111) plane. The results indicate that our Pt/Ir TFTCs have significant potential for application in many domains such as thermal detection, microelectronics and aero-engines.

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