Revisiting the plasmon radiation damping of gold nanorods

Noble metal nanoparticles have been utilized for a vast amount of optical applications. For applications that use metal nanoparticles as nanosensors and for optical labeling, higher radiative efficiency is preferred. To get a deeper knowledge about the radiation damping of noble metal nanoparticles, we used gold nanorods with different geometry factors (aspect ratios) as the model system to study. We investigated theoretically how the radiation damping of a nanorod depends on the material, and shape of the particle. Surprisingly, a simple analytical equation describes radiation damping very accurately and allows the disentanglement of the maximal radiation damping parameter for gold nanorods with resonance energy E-res around 1.81 eV (685 nm). We found very good agreement with theoretical predictions and experimental data obtained by single-particle spectroscopy. Our results and approaches may pave the way for designing and optimizing gold nanostructures with higher optical signal and better sensing performance.

Automated summary

In this study, gold nanorods were used as the model system to investigate the radiation damping properties of noble metal nanoparticles. Theoretical and experimental methods were employed, and it was found that radiation damping of the nanorods can be accurately described by a simple analytical equation. This research provides insights for designing and optimizing gold nanostructures with higher optical signal and better sensing performance.