Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 197, Issue 5-6, Pages 639-643Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2021.2011889
Keywords
1; 3; 5-Triaza-7-phosphaadamantane (PTA); ester derivative of PTA; P-sulfide ester derivative of PTA; kinetic resolution; hydrolysis
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Funding
- European Union
- European Regional Development Fund
- Foundation for Polish Science, Grant for Innovation upon Operational Programme-Innovative Economy, Priority 1: Research and development for new technologies, Measure 1.2: Improvement of the human potential of science
- Parent Bridge Programme [POMOST/2013-8/9]
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The enzyme-promoted hydrolysis of racemic ester derivatives of PTA 11 and its P-sulfide 12 resulted in unreacted esters and corresponding acids, with moderate yields depending on the solvent and enzyme used. However, the products obtained were racemic mixtures in all cases.
The enzyme-promoted hydrolysis of racemic ester derivatives of PTA 11 and its P-sulfide 12 gave unreacted esters and corresponding acids, which were converted into ester, in moderate yield depending on the solvent and enzyme applied. However, in all cases the products were racemic mixtures.
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