Journal
ORGANIC LETTERS
Volume 24, Issue 4, Pages 1017-1021Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c04161
Keywords
-
Categories
Funding
- Shenzhen Science and Technology Research and Development Funds [JCYJ20190806155409104]
- National Natural Science Foundation of China [21672130, 51773111, 52073163]
- State Key Laboratory of Crystal Materials
Ask authors/readers for more resources
Two BN-embedded benzo[ghi]perylene and coronene derivatives have been synthesized and their properties show significantly enhanced absorption and emission compared to their all carbon analogues. BN-Cor has a fluorescence quantum yield nearly 20 times higher than ordinary coronene.
Two BN-embedded benzo[ghi]perylene (Bzp) and coronene derivatives (BN-Bzp and BN-Cor) have been successfully synthesized from binaphthyl precursors by new efficient one-pot-multibond routes, and their single crystal structures were analyzed. Both experimental spectra and DFT theoretical calculations indicated that the absorption and emission of these BN-embedded polycyclic aromatic hydrocarbons are significantly enhanced comparing with those of their all carbon analogues. Especially, the fluorescence quantum yield of BN-Cor is nearly 20 times higher than that of ordinary coronene.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
