Journal
ORGANIC LETTERS
Volume 23, Issue 20, Pages 7938-7942Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02940
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Funding
- LabEx MiChem programme [ANR-11-IDEX-0004-02]
- Rotaximage project [ANR-16-CE09-0018]
- Agence Nationale de la Recherche (ANR) [ANR-16-CE09-0018] Funding Source: Agence Nationale de la Recherche (ANR)
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A family of cyclodextrins functionalized with different numbers of amines can control the rate of their threading and dethreading on a molecular axle based on pH and substitution pattern. The uniqueness of this system lies in the ability to directly control the switch rate by operating the stimulus on the macrocycle.
A family of cyclodextrins functionalized with zero, one, two, or six amines was shown to control the rate of their threading and dethreading on a molecular axle depending on the pH and their substitution pattern. The originality of this system lies in the rate control of the switch by operating the stimulus directly on the macrocycle.
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