Journal
ORGANIC LETTERS
Volume 24, Issue 8, Pages 1626-1630Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00125
Keywords
-
Categories
Funding
- ERC [716136:2O2ACTIVATION]
- DFG [SFB/TRR 88]
Ask authors/readers for more resources
Oxidative clicklike reactions are important for late-stage functionalization of pharmaceuticals and organic materials. The tellurium(II)-catalyzed cross-dehydrogenative phenothiazination described in this article benefits from a cooperative effect between the catalyst and silver salt, enabling a considerably broader scope compared to previous methods.
Oxidative clicklike reactions are useful for the late-stage functionalization of pharmaceuticals and organic materials. Hence, novel methodologies that enable such transformations are in high demand. Herein we describe a tellurium(II)-catalyzed cross-dehydrogenative phenothiazination (CDP) of aromatic amines. A key feature of this method is a cooperative effect between the phenotellurazine catalyst and the silver salt, which serves as a chemical oxidant for the reaction. This novel catalysis concept therefore enables a considerably broader scope compared with previous chemical oxidation methods.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available