Journal
ORGANIC LETTERS
Volume 23, Issue 20, Pages 7808-7813Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02831
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Funding
- Auburn University
- National Science Foundation [CHE2042353]
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Highly stereo- and enantioselective synthesis of (E)-delta-hydroxymethyl-anti-homoallylic alcohols is achieved through reactions between aldehydes and chiral nonracemic alpha-borylmethyl-(E)-crotylboronate, resulting in high E-selectivities and enantioselectivities.
Highly stereo- and enantioselective synthesis of (E)-delta-hydroxymethyl-anti-homoallylic alcohols is reported. Under the developed conditions, reactions between aldehydes and chiral nonracemic alpha-borylmethyl-(E)-crotylboronate upon oxidative workup gave delta-hydroxymethyl-anti-homoallylic alcohols with high E-selectivities and enantioselectivities.
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