Journal
ORGANIC LETTERS
Volume 23, Issue 21, Pages 8640-8644Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c03354
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Funding
- National Natural Science Foundation of China [22001135]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [20KJB480002]
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A nitrogenated derivative of Ovalene with all zigzag edges and nitrogen atom doping at the periphery has been successfully developed through one-step nitrogenation of formylbisanthene. These molecules exhibit decreased highest occupied molecular orbital levels, enhanced intermolecular interactions, and reversible acid response due to nitrogen incorporation. Additionally, the aza-ovalene also shows a diatropic ring current along the periphery, providing rare examples of all-zigzag-edged N-polycyclic aromatic hydrocarbons.
Ovalene's nitrogenated derivative with all zigzag edges and nitrogen atom doping at the periphery has been developed via one-step nitrogenation of formylbisanthene. Because of nitrogen incorporation, these molecules show greatly decreased highest occupied molecular orbital levels, enhanced intermolecular interactions, and a reversible acid response. Aza-ovalene also exhibits a diatropic ring current along the periphery. This work provides rare examples of all-zigzag-edged N-polycyclic aromatic hydrocarbons.
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