Journal
ORGANIC LETTERS
Volume 23, Issue 19, Pages 7603-7607Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02821
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Funding
- National Natural Science Foundation of China [22072178, 21825109, 21821002, 21732006]
- National Basic Research Program of China [2016YFA0202900]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB20000000]
- K. C. Wong Education Foundation
- Ningbo Municipal Bureau of Science and Technology [2019B10096]
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In this study, a pincer Ru-catalyzed dual intramolecular dehydrogenative silylation of primary C(sp(3))-H bonds was reported. The reaction demonstrated high efficiency, scalability, and good functional group tolerance, allowing for facile and atom-economical access to structurally diverse silicon-centered spirocycles, including unprecedented oxa-spirosilabiindanes and aza-spirosilabiindanes.
We report herein a pincer Ru-catalyzed dual intramolecular dehydrogenative silylation of primary C(sp(3))-H bonds. The reaction features high efficiency, scalability, and good functional group tolerance, allowing a facile and atom-economical access to structurally diverse silicon-centered spirocycles, including unprecedented oxa-spirosilabiindanes and aza-spirosilabiindanes.
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