4.6 Article

Flexible synthesis of high-performance electrode materials of N-doped carbon coating MnO nanowires for supercapacitors

Journal

NANOTECHNOLOGY
Volume 33, Issue 8, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1361-6528/ac394b

Keywords

MnO; C nanowires; Mn3O4; supercapacitor

Funding

  1. Anhui Provincial NaturalScience Foundation [.1908085MB37]

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MnO/C composites were prepared using a co-precipitation method and calcination at different temperatures. The study found that at 400 degrees C, the composites exhibited a uniformly dispersed nanowire structure with excellent electrochemical performance. Additionally, the potential application of MnO/C composites in asymmetric supercapacitors was demonstrated.
The MnO/C composites were obtained by co-precipitation method, which used Mn3O4 nanomaterials as precursors and dopamine solution after ultrasonic mixing and calcination under N-2 atmosphere at different temperatures. By studying the difference of MnO/C nanomaterials formed at different temperatures, it was found that with the increase of calcination temperature, the materials appear obvious agglomeration. The optimal calcination temperature is 400 degrees C, and the resulting MnO/C is a uniformly dispersed slender nanowire structure. The specific capacitance of MnO/C nanowires can reach 356 F g(-1) at 1 A g(-1). In the meantime, the initial capacitance of MnO/C nanowires remains 106% after 5000 cycles. Moreover, the asymmetric supercapacitor was installed, which displays a tremendous energy density of 30.944 Wh kg(-1) along with a high power density of 10 kW kg(-1). The composite material reveals a promising prospect in the application of supercapacitors.

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