Alleviating mechanical degradation of hexacyanoferrate via strain locking during Na+ insertion/extraction for full sodium ion battery

Generation of large strains upon Na+ intercalation is one of the prime concerns of the mechanical degradation of Prussian blue (PB) and its analogs. Structural construction from the atomic level is imperative to maintain structural stability and ameliorate the long-term stability of PB. Herein, an inter nickel hexacyanoferrate (NNiFCN) is successfully introduced at the out layer of iron hexacyanoferrate (NFFCN) through ion exchange to improve structural stability through compressive stress locking by forming NNiFCN shell. Furthermore, the kinetics of sodium ion diffusion is enhanced through the built-in electric pathway. The electrochemical performance is therefore significantly improved with a remarkable long-term cycling stability over 3,000 cycles at 500 mA.g(-1) in the full sodium-ion batteries (SIBs) with a maximum energy density of 91.94 Wh.g(-1), indicating that the core-shell structured NNiFCN/NFFCN could be the low-cost and high-performance cathode for full SIBs in large-scale EES applications.

Automated summary

Introducing nickel hexacyanoferrate (NNiFCN) onto the outer layer of iron hexacyanoferrate (NFFCN) through ion exchange improves structural stability and enhances the kinetics of sodium ion diffusion. As a result, the electrochemical performance is significantly improved with a remarkable long-term cycling stability, making NNiFCN/NFFCN core-shell structured cathode a promising candidate for full sodium-ion batteries in large-scale energy storage applications.