4.8 Article

Bright Mid-Wave Infrared Resonant-Cavity Light-Emitting Diodes Based on Black Phosphorus

Journal

NANO LETTERS
Volume 22, Issue 3, Pages 1294-1301

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.1c04557

Keywords

bP; LED; two-dimensional (2D) materials; parasitic resistance; light extraction efficiency; ITO

Funding

  1. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division [DE-AC02-05-CH11231, KC1201]
  2. Australian Research Council (ARC) Centre of Excellence for Transformative Meta-Optical Systems [CE200100010]
  3. ARC [DP210103428]

Ask authors/readers for more resources

This research demonstrates bP-LEDs with high quantum efficiencies and wall-plug efficiencies. By integrating an Al2O3/Au optical cavity and an ITO conducting oxide layer, the emission efficiency and performance of the devices are significantly improved.
The mid-wave infrared (MWIR) wavelength range plays a central role in a variety of applications, including optical gas sensing, industrial process control, spectroscopy, and infrared (IR) countermeasures. Among the MWIR light sources, light-emitting diodes (LEDs) have the advantages of simple design, room-temperature operation, and low cost. Owing to the low Auger recombination at high carrier densities and direct bandgap of black phosphorus (bP), it can serve as a high quantum efficiency emitting layer in LEDs. In this work, we demonstrate bP-LEDs exhibiting high external quantum efficiencies and wall-plug efficiencies of up to 4.43 and 1.78%, respectively. This is achieved by integrating the device with an Al2O3/Au optical cavity, which enhances the emission efficiency, and a thin transparent conducing oxide [indium tin oxide (ITO)] layer, which reduces the parasitic resistance, both resulting in order of magnitude improvements to performance.

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