4.6 Review

Advances in Palladium-Catalyzed Carboxylation Reactions

Journal

MOLECULES
Volume 27, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/molecules27010262

Keywords

carbon dioxide; carboxylation; catalysis; heterocycles; palladium

Funding

  1. MIUR [PRIN 2017YJMPZN]

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This short review highlights the progress in utilizing palladium-catalyzed carbon dioxide for synthesizing valuable organic molecules. The review is organized based on the type of substrate used in the Pd-catalyzed carboxylation process, including olefinic substrates, acetylenic substrates, and other substrates such as aryl halides and triflates.
In this short review, we highlight the advancements in the field of palladium-catalyzed carbon dioxide utilization for the synthesis of high value added organic molecules. The review is structured on the basis of the kind of substrate undergoing the Pd-catalyzed carboxylation process. Accordingly, after the introductory section, the main sections of the review will illustrate Pd-catalyzed carboxylation of olefinic substrates, acetylenic substrates, and other substrates (aryl halides and triflates).

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