4.6 Article

Gallic Acid Mitigates 5-Hydroxymethylfurfural Formation while Enhancing or Preserving Browning and Antioxidant Activity Development in Glucose/Arginine and Sucrose/Arginine Maillard Model Systems

Journal

MOLECULES
Volume 27, Issue 3, Pages -

Publisher

MDPI
DOI: 10.3390/molecules27030848

Keywords

maillard reaction; melanoidins; phenolic compounds; food thermal processes; FRAP; TEAC; HMF

Funding

  1. Fundacao Carlos Chagas Filho de Amparo a Pesquisa do Estado do Rio de Janeiro [E-26/211.149/2016, E-26/202.708, E-26/210.151/2018, E-26/210.003/2020]
  2. Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior-Brasil [001]

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The addition of gallic acid was found to mitigate the formation of 5-HMF in Maillard Reaction model systems, while also increasing color development and antioxidant activity, particularly in glucose/arginine and sucrose/arginine systems.
The current trend of lowering 5-hydroxymethylfurfural (5-HMF) dietary exposure is challenging since its formation is parallel with the development of food color, flavor and aroma. We aimed to investigate the effect of gallic acid (GA) addition on 5-HMF formation, color development and antioxidant activity (AA) in a series of Maillard Reaction (MR) model systems. The effects of GA addition on browning and AA development were not uniform for all model systems, but always occurred in the same direction, indicating that these phenomena were interconnected. GA mitigated 5-HMF development in four of the nine tested systems, possibly by preventing the oxidation of MR intermediates. Correlation analysis indicated that when GA addition mitigated 5-HMF formation, browning was either promoted or not affected. The proposed strategy was effective for glucose/arginine and sucrose/arginine systems, since GA mitigated 5-HMF formation (49% and 54%, respectively) in addition to increasing color development and antioxidant activity.

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