Journal
MOLECULES
Volume 26, Issue 22, Pages -Publisher
MDPI
DOI: 10.3390/molecules26226968
Keywords
biaryls; electrorganic synthesis; aryls coupling; electrodes; radical chemistry
Funding
- European Community-MSCA-ITN-EID project Technotrain: TECHNOTRAIN-H2020-MSCA-ITN-2018 Grant [812944]
- Marie Curie Actions (MSCA) [812944] Funding Source: Marie Curie Actions (MSCA)
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The review discusses the organic electrosynthesis of biaryls starting from phenols, anilines, naphthols, and naphthylamines, presenting significant examples from the last decade classified according to the single class of molecules.
Biaryl scaffolds are widely spread in biologically important natural products, in numerous therapeutic agents, but they are also considered a privileged class of ligands and (organo)catalysts; therefore, the development of efficient alternative methodologies to prepare such compounds is always attracting much attention. The present review discusses the organic electrosynthesis of biaryls starting from phenols, anilines, naphthols, and naphthylamines. The most significant examples of the works reported in the last decade are presented and classified according to the single class of molecules: after the introduction, the first three sections relate to the reactions of phenols, naphthols, and anilines, respectively; the other two sections refer to cross-coupling and miscellaneous reactions.
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