Journal
MOLECULES
Volume 27, Issue 2, Pages -Publisher
MDPI
DOI: 10.3390/molecules27020466
Keywords
triethylborane; reactivity ratios; anionic polymerization; degradable polymers; poly(ethylene oxide)
Funding
- KAUST under baseline funding [BAS/1/1374-01-01]
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The copolymerization of epoxides and anhydrides with the assistance of triethylborane can produce copolymers with high molar mass and containing ether and ester units. The reactivity ratio of epoxide can be adjusted by triethylborane, leading to different molar mass distributions of the resulting poly(ethylene oxide) diol samples.
The anionic ring-opening copolymerization (ROCOP) of epoxides, namely of ethylene oxide (EO), with anhydrides (AH) generally produces strictly alternating copolymers. With triethylborane (TEB)-assisted ROCOP of EO with AH, statistical copolymers of high molar mass including ether and ester units could be obtained. In the presence of TEB, the reactivity ratio of EO (r(EO)), which is normally equal to 0 in its absence, could be progressively raised to values lower than 1 or higher than 1. Conditions were even found to obtain r(EO) equal or close to 1. Samples of P(EO-co-ester) with minimal compositional drift could be synthesized; upon basic degradation of their ester linkages, these samples afforded poly(ethylene oxide) (PEO) diol samples of narrow molar mass distribution. In other cases where r(EO) were lower or higher than 1, the PEO diol samples eventually isolated after degradation exhibited a broader distribution of molar masses because of the compositional drift of initial P(EO-co-ester) samples.
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