Electrospun Nanofiber Membranes from 1,8-Naphthimide-Based Polymer/Poly(vinyl alcohol) for pH Fluorescence Sensing

Accurately and sensitively sensing and monitoring the pH in the environment is a key fundamental issue for human health. Nanomaterial and nanotechnology combined with fluorescent materials can be emerged as excellent possible methods to develop high-performance sensing membranes and help monitor pH. Herein, a series of fluorescent nanofiber membranes (NFMs) containing poly-1,8-naphthimide derivative-3-[dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azaniumyl]propane-1-sulfonate (PNI-SBMA) are fabricated by electrospinning the solution of PNI-SBMA blended with poly(vinyl alcohol) (PVA). The surfactant-like functionalities in side chains of PNI-SBMA endow the NFMs with outstanding hydrophilicity, and the naphthimide derivatives are sensitive to pH by photoinduced electron transfer effect, which contribute to highly efficient pH fluorescence sensing applications of NFMs. Specifically, the PNI-SBMA/PVA NFM with a ratio of 1:9 (NFM2) shows high sensitivity and good cyclability to pH. This work demonstrates an effective strategy to realize a fluorescent sensor NFM that has a fast and sensitive response to pH, which will benefit its application of pH sensor monitoring in the water treatment process.

Automated summary

Accurate and sensitive pH sensing and monitoring in the environment are crucial for human health. Nanomaterials and nanotechnology combined with fluorescent materials provide excellent opportunities for developing high-performance sensing membranes and monitoring pH effectively. In this study, fluorescent nanofiber membranes (NFMs) containing poly-1,8-naphthimide derivative-3-[dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azaniumyl]propane-1-sulfonate (PNI-SBMA) were fabricated by electrospinning. The NFMs showed outstanding hydrophilicity due to surfactant-like functionalities in the side chains of PNI-SBMA, and the naphthimide derivatives exhibited sensitivity to pH through the photoinduced electron transfer effect, enabling efficient pH fluorescence sensing applications of the NFMs. Among the NFMs, the PNI-SBMA/PVA NFM with a ratio of 1:9 (NFM2) demonstrated high sensitivity and good cyclability to pH.