4.7 Review

Self-quenching-resistant solid-state carbon dots for mechanism and applications

Journal

MICROCHIMICA ACTA
Volume 188, Issue 12, Pages -

Publisher

SPRINGER WIEN
DOI: 10.1007/s00604-021-05068-6

Keywords

Solid-state carbon dots; Photoluminescence; Fluorescence mechanism; Phosphorescence mechanism; Aggregation-induced quenching

Funding

  1. National Natural Science Foundation of China [51678409, 51638011, 51578375]
  2. Tianjin Research Program of Application Foundation and Advanced Technology of China [19JCYBJC19800, 18JCYBJC87500, 15ZCZDSF00880, 18JCYBJC89100]
  3. State Key Laboratory of Separation Membranes and Membrane Processes [Z1-201507]

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Traditional CDs suffer from aggregation-induced quenching, limiting the preparation and luminescence performance of SCDs. Current research aims to address this issue. SCDs have broad application prospects in luminescent devices, anti-counterfeiting, and detection fields.
Solid-state carbon dots (SCDs) have been widely investigated by scholars owing to their stability, environmental friendliness, and their good optical properties. The current studies on carbon dots (CDs) are mainly focused on the solutions of CDs, while the researches on SCDs are relatively few in comparison. Nowadays, the fabrication and design of high-performance SCDs have attracted much interest. However, due to resonance energy transfer and pi-pi interactions, CDs undergo aggregation-induced quenching (ACQ) phenomena. This poses an obstacle to the acquisition of SCDs and affects their luminescence performance. Publications of the past 5 years are reviewed on how to suppress the ACQ phenomenon and improve the fluorescence and phosphorescence emission of CDs (Ref. 87) and about the mechanism of achieving the luminescence of SCDs. Then, the applications of SCDs in the fields of luminescent devices, anti-counterfeiting, and detection are outlined. The concluding section analyzes the current challenges faced by SCDs and provides an outlook.

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