4.6 Article

A New Complementary Catalyst and Catalytic Mechanism: Ag2MoO4/Ag/AgBr/GO Heterostructure

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 55, Issue 37, Pages 9873-9879

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.6b01265

Keywords

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Funding

  1. National Natural Science Foundation China [21341007]
  2. Shanghai Key Laboratory of Multiphase Materials Chemical Engineering [MMCE2015002]

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The Ag2MoO4/Ag/AgBr/GO heterostructure photocatalyst is efficaciously designed and equipped, and it exhibits an excellent photocatalytic property. Tetracycline hydrochloride (TC-HCl) is degraded completely within 75 min by Ag2MoO4/Ag/AgBr/GO heterostructure under a 350 W Xe lamp cutting-off the UV light, in which the photocatalytic rate is 1.36 times higher than Ag2MoO4/Ag/AgBr composite. The photocatalytic activity is highly heightened, owing to the enhanced charge separation and topical SPR of Ag-0. In addition, GO in Ag2MoO4/Ag/AgBr/GO heterostructure further enlarges the delocalization of the charge transfer compared with Ag2MoO4/Ag/AgBr. After recycling eight times, the photocatalytic rate of Ag2MoO4/Ag/AgBr/GO only debases by 4.5%. Experimental results indicate the Ag2MoO4/Ag/AgBr/GO heterostructure has great potential application for dealing with TC-HCl residues in water.

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