Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 55, Issue 22, Pages 6492-6500Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.6b01045
Keywords
-
Categories
Funding
- ARO [W911NF-10-1-0076]
- U.S. DOE Office of Science as part of the Center for Understanding and Control of Acid Gas Evolution of Materials for Energy, an Energy Frontier Research Center - US Department of Energy, Office of Science, Basic Energy Sciences [DE-SC0012577]
Ask authors/readers for more resources
A hydrotalcite-derived MgAl oxide (MMO) was evaluated in combination with the metal-organic frameworks (MOFs) UiO-66 and UiO-66-NH2 for the adsorption of ammonia. Analysis of the materials textural properties after ammonia breakthrough adsorption revealed no change in the PXRD patterns or FTIR spectra; however, a slight decrease in surface area was observed, consistent with the hypothesized presence of strongly adsorbed species after adsorption. UiO-66:MMO and UiO-66-NH2:MMO composites maintained ammonia adsorption capacity under dry conditions. An almost 2-fold increase in humid ammonia capacity was observed for the UiO-66:MMO composite, far beyond that expected through a linear combination of the two materials capacities. The synergistic effect observed in humid conditions was further investigated with water adsorption experiments, which suggested the effect is the result of the high water affinity of MMO.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
