4.6 Article

Mechanical characteristics and in vitro degradation of biodegradable Zn-Al alloy

Journal

MATERIALS LETTERS
Volume 300, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2021.130181

Keywords

Biomaterials; Zn alloys; Superplasticity; Immersion; Corrosion

Funding

  1. Joint Program of Beijing MunicipalBeijing Natural Science Foundation [KZ202110005004]

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In this study, a Zn-5wt.%Al alloy tube was prepared, showing high elongation to failure and medium strength. The superplasticity of the alloy is attributed to its unique microstructure. Additionally, the extruded alloy exhibited a higher corrosion rate in the corrosion test.
Zn-5wt.%Al alloy was cast and extruded into the tube in the present work. The mechanical properties and degradation behavior of as-cast and extruded alloys were investigated. Compared with other binary Zn alloys, the extruded Zn-5wt.%Al alloy tube showed a ultra-high elongation to failure (383.3%) and medium strength (257 MPa). The superplasticity is attributed to the grain boundary slip due to unique microstructure, i.e. the ultrafinegrained alpha-phase accumulated mainly along the fine-grained eta-phase boundary. Furthermore, after 32 days' immersion, the corrosion rates of as-cast and extruded alloy were 0.11 mm/y and 0.15 mm/y, respectively. The electrochemical polarization test and corrosion surface analysis indicate an initial ultrafine-grained Al-rich phase dissolution for extruded Zn-5wt.%Al alloy.

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