Multifunctional feature of double perovskite strontium iron vanadate for storage device

In this report, we have investigated the structure, vibration, optical, dielectric, transport and magnetic features of the double perovskite Sr2FeVO6. The structural investigation of the sample is done by incorporating X-ray diffraction (XRD) and scanning electron microscopic (SEM) technique at room temperature. The structural investigation suggests the formation of a single phase polycrystalline sample having monoclinic symmetry. The chemical composition and valence of the involved elements are investigated by incorporating the X-ray photoelectron spectroscopic (XPS) technique. The dual oxidation state of Fe is revealed through the XPS investigation. The vibrational property of the sample is analyzed through both Raman and FTIR spectroscopic methods. The various modes of vibrations such as symmetric, anti-symmetric and bending modes are illustrated through Raman and FTIR techniques. Analysis of optical spectrum and energy bandgap of the sample is done by UV-Visible spectroscopic technique. The bandgap (E-g = 2.88 eV) of the material is found suitable for photo catalytic activities. The dielectric spectrum of the sample is analyzed by investigating the variation of dielectric parameters, that is epsilon(r) and tan delta, w.r.t frequency-temperature. The dielectric spectrum is found consistent with Maxwell-Wagner model. The electrical and transport activities in the material are investigated by analyzing the spectra of impedance, modulus and AC conductivity at varying frequencies and temperatures. The relaxation feature of the material is illustrated through impedance and modulus spectroscopic techniques whereas the significant contribution of hopping conduction mechanism is depicted through AC conductivity spectra. Finally, the ferromagnetic property of the material at room temperature is clarified through the hysteresis curve.

Automated summary

This report investigates the structure, vibration, optical, dielectric, transport, and magnetic features of double perovskite Sr2FeVO6. Multiple techniques such as XRD, SEM, XPS, Raman, FTIR, and UV-Visible spectroscopy are employed to study the material, revealing its monoclinic structure, dual oxidation state of Fe, suitable bandgap for photocatalytic activities, dielectric behavior consistent with Maxwell-Wagner model, and the contribution of hopping conduction mechanism to its transport properties. Furthermore, the ferromagnetic property of the material is confirmed through hysteresis curve analysis.