4.6 Article

Compositing of MIL-101(Fe) with reduced graphene oxide and polyaniline for capacitive energy storage

Journal

MATERIALS CHEMISTRY AND PHYSICS
Volume 278, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2021.125641

Keywords

MIL-101(Fe); Nanocomposites; Supercapacitor

Funding

  1. Krklareli University, Turkey [KLUBAP-139]

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Metal-organic frameworks (MOFs) have attracted attention in electrochemistry for their high porosity and potential high charge storage abilities. A new nanocomposite material based on MIL-101(Fe) was synthesized with reduced graphene oxide (rGO) and polyaniline (PANI). The electrochemical properties of the composites in different electrolytes were investigated, and it was found that rGO/MIL-101(Fe) exhibited the highest specific capacitance in alkaline electrolyte.
Metal-organic frameworks (MOFs) have attracted attention for various applications in electrochemistry due to their high porosity and potential high charge storage abilities. New MIL-101(Fe)-based nanocomposite materials were synthesized with reduced graphene oxide (rGO) and polyaniline (PANI). The prepared composites were characterized by various techniques. The electrochemical properties of the materials were investigated in 1 M Na2SO4 and 2 M KOH as electrolytes. To the best of our knowledge, the capacitive energy storage properties of rGO/MIL-101(Fe)/PANI as a supercapacitor electrode is reported for the first time. Among the prepared compounds, rGO/MIL-101(Fe) in alkaline electrolyte exhibited the highest specific capacitance of 250.63 F/g at 0.5 A/g which has very low charge transfer resistance of 0.141 Omega. Compared to rGO/MIL-101(Fe), rGO/MIL-101(Fe)/ PANI exhibited higher capacitance in neutral electrolyte, while showed lower capacitance in alkaline electrolyte. The capacitive properties of MIL-101(Fe) based composite electrodes were found to greatly depend on charge transfer processes, obtained by detailed analyses and EIS measurements.

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