Journal
LETTERS IN ORGANIC CHEMISTRY
Volume 19, Issue 8, Pages 677-681Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570178619666220112124054
Keywords
Isosteviol; asymmetric catalysis; organocatalyst; squaramide; michael reaction; nitroalkenes
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Funding
- National Natural Science Foundation of China [NSFC 51403053]
- Natural Science Foundation of Henan province [202300410188, 212300410152]
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This study demonstrates the application of isosteviol-derived bifunctional primary amine-squaramide organocatalysts in the Michael addition reaction between nitroalkenes and acetophenone, yielding high yields and good enantioselectivity at room temperature.
The isosteviol derived bifunctional primary amine-squaramide organocatalysts were applied in the Michael addition between nitroalkenes and acetophenone. The conjugate addition isomers of two configurations were observed with high yields (up to 93% yield) and good enantioselectivity (up to 91% ee) at room temperature.
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