Ultrafast high-temperature sintering of silicon nitride: A comparison with the state-of-the-art techniques

Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate the silicon nitride (Si3N4) bulks, as the first attempt of ultra-rapid consolidation of a non-oxide ceramics. At a heating rate of 875 degrees C/min, the bulk Si3N4 ceramic with a relative density greater than 96 % and an alpha-beta phase transformation degree above 80 % could be obtained within 300 s. The effects of ultrafast heating on the liquid phase sintering (LPS) were also comparatively studied. Results showed that, the ultrafast heating rate and high temperature under UHS might promote the LPS system evolving to a nonequilibrium state. By comparing with other pressureless sintering processes with much lower heating rates, UHS apart from reducing the processing time, and it is also an effective method to form a bimodal microstructure composed of interlocked rod-like beta-Si3N4 grains.

Automated summary

Ultrafast High-temperature Sintering (UHS) has been successfully applied to fabricate silicon nitride (Si3N4) bulks in a short period of time, achieving high density and promoting the evolution of the liquid phase sintering system towards a nonequilibrium state.