4.7 Article

Hydrophobic mullite ceramic hollow fibre membrane (Hy-MHFM) for seawater desalination via direct contact membrane distillation (DCMD)

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 41, Issue 13, Pages 6578-6585

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.06.024

Keywords

Mullite; Ceramic membrane; Direct contact membrane distillation; Seawater desalination; Hydrophobic membrane

Funding

  1. Ministry of Higher Education Malaysia under the Fundamental Research Grant Scheme [R.J130000.7809.5F161]
  2. Malaysia Research University Network (MRUN) [R.J130000.7809.4L867]
  3. Higher Institution Centre of Excellence Scheme [R.J090301.7809.4J430]
  4. Ministry of Science, Technology and Innovation (MOSTI), Malaysia under International Collaboration Fund (ICF) [IF0120I1164]
  5. Universiti Teknologi Malaysia under the UTM High Impact Research Grant [Q.J130000.2409.08G34]
  6. Universiti Teknologi Malaysia under Collaborative Research Grant (CRG) [R.J130000.7351.4B440]

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A low-cost hydrophobic mullite hollow fibre membrane was successfully fabricated and characterized in this study, showing excellent desalination performance and long-term stability under high salt concentration conditions.
A low-cost hydrophobic mullite hollow fibre membrane (Hy-MHFM) fabricated via phase inversion/sintering technique followed by fluoroalkyl silane (FAS) grafting is presented in this study. The prepared CHFMs were characterized before and after the grafting step using different characterization techniques. The pore size of the CHFM surface was also determined using ImageJ software. The desalination performance of the grafted membrane was evaluated in direct contact membrane distillation (DCMD) using synthetic seawater of varying salt concentrations for 2 h at various feedwater temperatures. The outcome of the evaluations showed declines in the permeate flux of the membrane at increasing feed concentration, as well as increased flux with increased feed temperature. The long-term stability of the membrane was achieved at time 20 h, feed temperature 60 degrees C, and permeate temperature 10 degrees C, the membrane achieved a salt rejection performance of about 99.99 % and a water flux value of 22.51 kg/ m(2)h.

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