4.7 Article

Eu2+ activated NaBa3Si2O7F: A new efficient blue-emitting luminescent material for solid-state lighting and display

Journal

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 105, Issue 2, Pages 1095-1105

Publisher

WILEY
DOI: 10.1111/jace.18136

Keywords

cathodoluminescence; FED; luminescent materials; photoluminescence; WLED

Funding

  1. National Natural Science Foundation of China [U1905213]

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A novel efficient blue-emitting phosphor, Eu2+ doped barium-containing silicate fluoride NaBa3Si2O7F, was synthesized with excellent luminescence and thermal stability, showing great potential for practical application in white light-emitting diodes. Furthermore, the phosphor also exhibited good cathodoluminescence properties for potential use in field emission displays.
Exploring novel efficient phosphors for lighting and display has always been an important and meaningful work for researchers. Herein, a novel efficient blue-emitting phosphor, Eu2+ doped barium-containing silicate fluoride NaBa3Si2O7F, was prepared by solid-state method. The phosphor can produce bright blue light peaked at 452 nm with full-width at half-maximum about 57 nm under near-UV light excitation, and it exhibits a high internal quantum yield about 76.23%. The temperature-dependent photoluminescence spectra show that this phosphor owns good thermal stability, and the emission intensity at 425 K is 67% of that at room temperature. The outstanding data of fabricated device demonstrate that the blue phosphor has large possibility of practical application for white light-emitting diode. Furthermore, the phosphor also possesses good cathodoluminescence properties under various accelerating voltage with different probe currents, indicating its potential application in field emission displays.

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