Hierarchically mesoporous mixed copper oxide/calcined layered double hydroxides composites for iodide high-efficiency elimination

The leakage of iodide (I-)-containing wastewater into environment could cause water pollution owing to the toxicity and radioactivity of iodine isotopes. Therefore, multifunctional adsorbents with high-efficiency removal toward iodide are in high demanded. In the present research, the hierarchically mesoporous mixed copper oxide anchored on calcined layered double hydroxide (Cu2O/CuO@CLDH) materials were synthesized by direct pyrolysis of Cu-BTC metal-organic framework @ layered double hydroxide (HKUST-1@LDH) under N-2. Subsequently, the resultant materials were characterized and applied to remove iodide from simulated wastewater. The batch adsorption experiments showed a high I- adsorption amount of 120.9 mg/g with relatively fast kinetic removal process as well as good selectivity, and wide working pH range. The adsorption behavior, with spontaneity and exothermic, matched well with the Langmuir isotherm and pseudo-second-order kinetic models, which suggests a homogenous monolayer adsorption and chemisorption characteristics of the as-fabricated materials toward iodide. The outstanding adsorption performance of Cu2O/CuO@CLDH could be attributed to the reconstruction of the layered structures of CLDH and the strong chemical interaction between Cu2O and I-. This study proposes a promising material for iodide elimination.

Automated summary

The study synthesized Cu2O/CuO@CLDH materials for iodide removal from simulated wastewater, showing high adsorption performance with an adsorption amount of 120.9 mg/g, fast adsorption kinetics, good selectivity, and a wide working pH range. This material demonstrated homogeneous monolayer adsorption and chemisorption characteristics towards iodide, with outstanding performance attributed to the reconstructed layered structures of CLDH and strong chemical interaction with Cu2O.