4.5 Article

Adsorption of strontium (II) ions from aqueous solution onto bottom ash of expired drug incineration

Journal

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 330, Issue 3, Pages 929-940

Publisher

SPRINGER
DOI: 10.1007/s10967-021-08054-7

Keywords

Adsorption; BAEDI; Ions strontium; Isotherm model; Kinetics models

Funding

  1. CRNB (Nuclear Research Center of Birine)
  2. Yahia Fares University of Algeria

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The study used Bottom Ash of Expired Drug Incineration (BAEDI) for the removal of Sr(II), finding that the pseudo-second order and ninth order models fit the data, and the thermodynamic study indicated a spontaneous, endothermic process with increased affinity for Sr2+. The adsorption of Sr2+ was found to be of a physical nature, and the Langmuir model calculated a maximum adsorption capacity of 38 mgg(-1).
Bottom Ash of Expired Drug Incineration (BAEDI) is used in this study for the removal of Sr(II). In the kinetic study, the experimental results are tested. The results obtained show that the pseudo-second order and ninth order models fit the data. Thermodynamic study suggests that the process is: spontaneous, endothermic and with a raised affinity for Sr2+. The results obtained (Delta H degrees = 37.58 kJ mol(-1), E-a = 21.35 kJ mol(-1)) show that the adsorption of Sr2+ is a physical nature. Statistical analysis and the parameters obtained, revealed that the models used are suitable for the data. The maximum adsorption capacity (q(m)), calculated by using Langmuir model, is 38 mgg(-1).

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