4.8 Article

A Modified SiO2-Based Memristor with Reliable Switching and Multifunctional Synaptic Behaviors

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 13, Issue 3, Pages 884-893

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.1c03912

Keywords

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Funding

  1. National Science Funds [61822106]
  2. Natural Science Foundation of China [U19A2070, 62074025]

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By constructing a passivated layer of SiO2 using Ag-doped SrTiO3, the endurance and stability of SiO2-based memory have been improved, allowing for the implementation of various synaptic functions. Experimental results demonstrate the reliable operation of the modified memristor in an ambient environment, offering a new solution for neuromorphic computing.
Dielectric SiO2 has possible uses as an active layer for emerging memory due to its high on/off ratio and low operation voltage. However, SiO2-based memory that relies on the conducting filament still has limited endurance and stability. Here, we have constructed a passivated layer of SiO2 using Ag-doped SrTiO3, which serves as a Ag ion reservoir for the control of filament formation. It is demonstrated that the modified memristor presents an excellent endurance switching and could stably be operated in an ambient environment for 20 days without visible degradation. Based on the reliable switching, the synaptic functions such as excitatory postsynaptic current, paired-pulse facilitation, transition from short-term memory to long-term memory, and potentiation/depression have also been implemented. Furthermore, a 7 x 7 pixel array made from memristors has successfully mimicked simple learning and forgetting behavior. The experimental results offer an alternative approach for SiO2-based memristors and a possibility to be applied in neuromorphic computing.

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