4.6 Article

Magnetic Properties of the Hexagonal Ferromagnet NdCrGe3 Showing Metamagnetic Transition and Negative Magnetocaloric Effect

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 125, Issue 42, Pages 23370-23382

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.1c06285

Keywords

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Funding

  1. National Natural Science Foundation of China [11804141]
  2. Key Scientific and Technological Projects of Henan Province [182102310650, 202102210120]
  3. Key Scientific Research Program of Higher Education of Henan Province [21A510008]

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The single crystals of hexagonal ferromagnet NdCrGe3 with one-dimensional crystal structure exhibit large magnetic anisotropy and complex magnetic structure. Besides the ferromagnetic transition at T-C = 101 K, there are sharp decreases in magnetization at T = 55 K and two additional phase transitions at T = 31 and 15 K. Below T = 55 K, metamagnetic transitions and negative magnetocaloric effects are detected under H//ab. Critical properties around T-C = 101 K and anisotropic magnetocaloric effect are investigated in detail.
Single crystals of a hexagonal ferromagnet NdCrGe3 with one-dimensional crystal structure are synthesized, and the magnetic properties are comprehensively investigated, exhibiting large magnetic anisotropy and complex magnetic structure. Besides the ferromagnetic transition at T-C = 101 K, we observe a sharp decrease in magnetization at T = 55 K and another two phase transitions at T = 31 and 15 K. These phase transitions imply complex and anisotropic magnetic structure in NdCrGe3. Below T = 55 K, metamagnetic transitions and negative magnetocaloric effects are detected under H//ab. Additionally, the critical properties around T-C = 101 K and the anisotropic magnetocaloric effect are investigated in detail.

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