4.6 Article

Electrodeposition of GeSbTe-Based Resistive Switching Memory in Crossbar Arrays

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 125, Issue 47, Pages 26247-26255

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.1c08549

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Funding

  1. EPSRC [EP/N035437/1]

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This work presents resistive random-access memory cells fabricated using electrodeposited GeSbTe material in a crossbar architecture, showing asymmetric bipolar resistive switching characteristics and multi-state switching behavior. The switching between high-resistance and low-resistance states in these cells is attributed to the formation and rupture of conductive Te bridges within the Te-rich GeSbTe matrix under high electric field.
In this work, we report on the fabrication of resistive random-access memory cells based on electrodeposited GeSbTe material between TiN top and bottom electrodes in a crossbar architecture. The cells exhibit asymmetric bipolar resistive switching characteristics under the same SET and RESET compliance current (CC), showing highly uniform and reproducible switching properties. A multi-state switching behavior can be also achieved by varying the sweeping voltage and CC. Unlike phase-change switching, the switching between the high-resistance state and the low-resistance state in these cells can be attributed to the formation and rupture of conductive Te bridge(s) within the Te-rich GeSbTe matrix upon application of a high electric field. The results point toward the usage of the electrodeposition method to fabricate advanced functional device structures for application in non-volatile memory.

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