Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 125, Issue 47, Pages 13003-13014Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.1c07439
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Funding
- Laboratory Directed Research and Development Program [218253]
- U.S. Department of Energy's National Nuclear Security Administration [DE-NA-0003525]
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Ionogels are composite materials with unique attributes that make them promising for electrochemical energy storage applications. This study found that the morphology of the confining matrix and solid volume fraction can impact ionic conductivity and Li+ diffusivity. Low-silica ionogels with wide pores generally exhibit the best transport properties at high temperatures.
Ionogels (IGs) are a unique class of composite materials with attributes that make them promising materials for applications in electrochemical energy storage. Due to the solid porous matrix that confines the ionic liquid (IL) in the IG, they can be used as self-supporting electrolytes. Furthermore, interactions of the IL with the porous matrix can have beneficial effects on transport, such as lowering the freezing/glass transition temperature of the conducting IL. In this work, we employ molecular dynamics simulations to investigate the influence of the porous morphology and solid volume fraction on ionic conductivity and Li+ diffusivity using a representative 0.5 M Li-bis(trifluoromethane)sulfonimide (TFSI)-pyrrolidinium (Pyr1.3) IL confined in a nanoporous silica matrix. The effect of the morphology of the confining matrix is compared using the pure IL as a baseline. We find that the tracer and collective Li+ diffusion and ionic conductivity of all the model IGs have significantly lower temperature dependence than the corresponding pure IL. In general, low-silica IGs with wide pores displayed the best transport properties at high temperatures, but the trends with the morphology for the nested set of transport coefficients we examined changed as the collective behavior of the Li+ ions and the molecular IL components were considered. Remarkably, some of the model IGs displayed better transport properties on a volume of fluid basis at low temperatures than the constituent IL. These trends were tied to structural changes revealed by the radial distribution functions of the IL components and the silica surface, including a decreasing Li+ adsorption peak of the surface silica indicating a change in the relative contributions of bulk-like and surface-like transport in the confined IL.
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