Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 422, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2021.113549
Keywords
Fluorimetric sensor; Colorimetric sensor; Amine sensor; BODIPY; Substitution reaction
Categories
Funding
- Hacettepe University [FDK-2018-17171]
- Presidency of the Republic of Turkey, Presidency of Strategy [2016K 121230]
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The usability of BrBDP in colorimetric/fluorimetric determination, discrimination, and quantification was investigated, revealing its ability to distinguish amines based on their structural properties. The chemodosimeter showed high selectivity towards tested functional groups and could be used for detecting volatile amines. Furthermore, it was proven to be effective in detecting biogenic amines released from spoiled chicken meat.
The usability of 2,3,5,6-tetrabromo-8-phenyl BODIPY (BrBDP) for colorimetric/fluorimetric determination, discrimination, and quantification was investigated. The addition of an amine compound to the solution of BrBDP in acetonitrile caused dramatic changes in the photophysical properties and the color of the solution. These observed changes were specific to the structure of the amine, giving the chemodosimeter the ability to distinguish amines based on their structural properties Other tested functional groups (ethanol, phenol, acetone, formaldehyde, DMF, diethyl ether, ethyl acetate, and acetic acid) resulted in minimal or no change in the photophysical properties of the chemodosimeter indicating it to be highly selective. BrBDP-adsorbed TLC plates were shown to be used as test strips for the detection of volatile amines. Biogenic amines released from spoiled chicken meat were detected by this test strip.
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